Californium

Californium is a synthetic chemical element; it has symbol Cf and atomic number 98. It was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory) by bombarding curium with alpha particles (helium-4 ions). It is an actinide element, the sixth transuranium element to be synthesized, and has the second-highest atomic mass of all elements that have been produced in amounts large enough to see with the naked eye (after einsteinium). It was named after the university and the U.S. state of California.

Californium, 98Cf
Californium
Pronunciation/ˌkæləˈfɔːrniəm/ (KAL-ə-FOR-nee-əm)
Appearancesilvery
Mass number[251]
Californium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Dy

Cf

(Upb)
berkeliumcaliforniumeinsteinium
Atomic number (Z)98
Groupf-block groups (no number)
Periodperiod 7
Block  f-block
Electron configuration[Rn] 5f10 7s2
Electrons per shell2, 8, 18, 32, 28, 8, 2
Physical properties
Phase at STPsolid
Melting point1173 K (900 °C, 1652 °F)
Boiling point1743 K (1470 °C, 2678 °F) (estimation)
Density (near r.t.)15.1 g/cm3
Atomic properties
Oxidation states+2, +3, +4, +5
ElectronegativityPauling scale: 1.3
Ionization energies
  • 1st: 608 kJ/mol
Spectral lines of californium
Other properties
Natural occurrencesynthetic
Crystal structure double hexagonal close-packed (dhcp)
Mohs hardness3–4
CAS Number7440-71-3
History
Namingafter California, where it was discovered
DiscoveryLawrence Berkeley National Laboratory (1950)
Isotopes of californium
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
248Cf synth 333.5 d α100% 244Cm
SF<0.01%
249Cf synth 351 y α100% 245Cm
SF≪0.01%
250Cf synth 13.08 y α99.9% 246Cm
SF0.08%
251Cf synth 898 y α 247Cm
252Cf synth 2.645 y α96.9% 248Cm
SF3.09%
253Cf synth 17.81 d β99.7% 253Es
α0.31% 249Cm
254Cf synth 60.5 d SF99.7%
α0.31% 250Cm

Two crystalline forms exist at normal pressure: one above and one below 900 °C (1,650 °F). A third form exists at high pressure. Californium slowly tarnishes in air at room temperature. Californium compounds are dominated by the +3 oxidation state. The most stable of californium's twenty known isotopes is californium-251, with a half-life of 898 years. This short half-life means the element is not found in significant quantities in the Earth's crust. 252Cf, with a half-life of about 2.645 years, is the most common isotope used and is produced at Oak Ridge National Laboratory in the United States and Research Institute of Atomic Reactors in Russia.

Californium is one of the few transuranium elements with practical applications. Most of these applications exploit the property of certain isotopes of californium to emit neutrons. For example, californium can be used to help start up nuclear reactors, and it is employed as a source of neutrons when studying materials using neutron diffraction and neutron spectroscopy. It can also be used in nuclear synthesis of higher mass elements; oganesson (element 118) was synthesized by bombarding californium-249 atoms with calcium-48 ions. Users of californium must take into account radiological concerns and the element's ability to disrupt the formation of red blood cells by bioaccumulating in skeletal tissue.

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