Beryllium

Beryllium is a chemical element; it has symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form minerals. Gemstones high in beryllium include beryl (aquamarine, emerald, red beryl) and chrysoberyl. It is a relatively rare element in the universe, usually occurring as a product of the spallation of larger atomic nuclei that have collided with cosmic rays. Within the cores of stars, beryllium is depleted as it is fused into heavier elements. Beryllium constitutes about 0.0004 percent by mass of Earth's crust. The world's annual beryllium production of 220 tons is usually manufactured by extraction from the mineral beryl, a difficult process because beryllium bonds strongly to oxygen.

Beryllium, 4Be
Beryllium
Pronunciation/bəˈrɪliəm/ (bə-RIL-ee-əm)
Appearancewhite-gray metallic
Standard atomic weight Ar°(Be)
  • 9.0121831±0.0000005
  • 9.0122±0.0001 (abridged)
Beryllium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson


Be

Mg
lithium ← berylliumboron
Atomic number (Z)4
Groupgroup 2 (alkaline earth metals)
Periodperiod 2
Block  s-block
Electron configuration[He] 2s2
Electrons per shell2, 2
Physical properties
Phase at STPsolid
Melting point1560 K (1287 °C, 2349 °F)
Boiling point2742 K (2469 °C, 4476 °F)
Density (at 20° C)1.845 g/cm3
when liquid (at m.p.)1.690 g/cm3
Critical point5205 K,  MPa (extrapolated)
Heat of fusion12.2 kJ/mol
Heat of vaporization292 kJ/mol
Molar heat capacity16.443 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1462 1608 1791 2023 2327 2742
Atomic properties
Oxidation states0, +1, +2 (an amphoteric oxide)
ElectronegativityPauling scale: 1.57
Ionization energies
  • 1st: 899.5 kJ/mol
  • 2nd: 1757.1 kJ/mol
  • 3rd: 14,848.7 kJ/mol
  • (more)
Atomic radiusempirical: 112 pm
Covalent radius96±3 pm
Van der Waals radius153 pm
Spectral lines of beryllium
Other properties
Natural occurrenceprimordial
Crystal structure hexagonal close-packed (hcp) (hP2)
Lattice constants
a = 228.60 pm
c = 358.42 pm (at 20 °C)
Thermal expansion10.98×10−6/K (at 20 °C)
Thermal conductivity200 W/(m⋅K)
Electrical resistivity36 nΩ⋅m (at 20 °C)
Magnetic orderingdiamagnetic
Molar magnetic susceptibility−9.0×10−6 cm3/mol
Young's modulus287 GPa
Shear modulus132 GPa
Bulk modulus130 GPa
Speed of sound thin rod12,890 m/s (at r.t.)
Poisson ratio0.032
Mohs hardness5.5
Vickers hardness1670 MPa
Brinell hardness590–1320 MPa
CAS Number7440-41-7
History
DiscoveryLouis Nicolas Vauquelin (1798)
First isolationFriedrich Wöhler & Antoine Bussy (1828)
Isotopes of beryllium
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
7Be trace 53.22 d ε 7Li
8Be synth 81.9 as α 4He
9Be 100% stable
10Be trace 1.387×106 y β 10B

In structural applications, the combination of high flexural rigidity, thermal stability, thermal conductivity and low density (1.85 times that of water) make beryllium metal a desirable aerospace material for aircraft components, missiles, spacecraft, and satellites. Because of its low density and atomic mass, beryllium is relatively transparent to X-rays and other forms of ionizing radiation; therefore, it is the most common window material for X-ray equipment and components of particle detectors. When added as an alloying element to aluminium, copper (notably the alloy beryllium copper), iron, or nickel, beryllium improves many physical properties. For example, tools and components made of beryllium copper alloys are strong and hard and do not create sparks when they strike a steel surface. In air, the surface of beryllium oxidizes readily at room temperature to form a passivation layer 1–10 nm thick that protects it from further oxidation and corrosion. The metal oxidizes in bulk (beyond the passivation layer) when heated above 500 °C (932 °F), and burns brilliantly when heated to about 2,500 °C (4,530 °F).

The commercial use of beryllium requires the use of appropriate dust control equipment and industrial controls at all times because of the toxicity of inhaled beryllium-containing dusts that can cause a chronic life-threatening allergic disease in some people called berylliosis. Berylliosis causes pneumonia and other associated respiratory illness.

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