Copper(I) chloride

Copper(I) chloride, commonly called cuprous chloride, is the lower chloride of copper, with the formula CuCl. The substance is a white solid sparingly soluble in water, but very soluble in concentrated hydrochloric acid. Impure samples appear green due to the presence of copper(II) chloride (CuCl2).

Copper(I) chloride
Names
IUPAC name
Copper(I) chloride
Other names
Cuprous chloride
Identifiers
3D model (JSmol)
8127933
ChEBI
ChemSpider
DrugBank
ECHA InfoCard 100.028.948
EC Number
  • 231-842-9
13676
PubChem CID
RTECS number
  • GL6990000
UNII
  • InChI=1S/ClH.Cu/h1H;/q;+1/p-1 Y
    Key: OXBLHERUFWYNTN-UHFFFAOYSA-M Y
  • InChI=1/ClH.Cu/h1H;/q;+1/p-1
    Key: OXBLHERUFWYNTN-REWHXWOFAC
SMILES
  • Cl[Cu]
Properties
CuCl
Molar mass 98.999 g/mol
Appearance white powder, slightly green from oxidized impurities
Density 4.14 g/cm3
Melting point 423 °C (793 °F; 696 K)
Boiling point 1,490 °C (2,710 °F; 1,760 K) (decomposes)
0.047 g/L (20 °C)
Solubility product (Ksp)
1.72×10−7
Solubility insoluble in ethanol,
acetone; soluble in concentrated HCl, NH4OH
Band gap 3.25 eV (300 K, direct)
Magnetic susceptibility (χ)
-40.0·10−6 cm3/mol
Refractive index (nD)
1.930
Structure
Zincblende, cF20
Space group
F43m, No. 216
a = 0.54202 nm
0.1592 nm3
4
Hazards
GHS labelling:
Warning
H302, H410
P264, P270, P273, P301+P312, P330, P391, P501
NFPA 704 (fire diamond)
3
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
140 mg/kg
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)
REL (Recommended)
TWA 1 mg/m3 (as Cu)
IDLH (Immediate danger)
TWA 100 mg/m3 (as Cu)
Safety data sheet (SDS) JT Baker
Related compounds
Other anions
Copper(I) fluoride
Copper(I) bromide
Copper(I) iodide
Other cations
Silver(I) chloride
Gold(I) chloride
Related compounds
Copper(II) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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