Copper(I) chloride
Copper(I) chloride, commonly called cuprous chloride, is the lower chloride of copper, with the formula CuCl. The substance is a white solid sparingly soluble in water, but very soluble in concentrated hydrochloric acid. Impure samples appear green due to the presence of copper(II) chloride (CuCl2).
Names | |
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IUPAC name
Copper(I) chloride | |
Other names
Cuprous chloride | |
Identifiers | |
3D model (JSmol) |
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8127933 | |
ChEBI | |
ChemSpider | |
DrugBank | |
ECHA InfoCard | 100.028.948 |
EC Number |
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13676 | |
PubChem CID |
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RTECS number |
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UNII | |
CompTox Dashboard (EPA) |
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SMILES
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Properties | |
CuCl | |
Molar mass | 98.999 g/mol |
Appearance | white powder, slightly green from oxidized impurities |
Density | 4.14 g/cm3 |
Melting point | 423 °C (793 °F; 696 K) |
Boiling point | 1,490 °C (2,710 °F; 1,760 K) (decomposes) |
0.047 g/L (20 °C) | |
Solubility product (Ksp) |
1.72×10−7 |
Solubility | insoluble in ethanol, acetone; soluble in concentrated HCl, NH4OH |
Band gap | 3.25 eV (300 K, direct) |
Magnetic susceptibility (χ) |
-40.0·10−6 cm3/mol |
Refractive index (nD) |
1.930 |
Structure | |
Zincblende, cF20 | |
Space group |
F43m, No. 216 |
a = 0.54202 nm | |
Lattice volume (V) |
0.1592 nm3 |
Formula units (Z) |
4 |
Hazards | |
GHS labelling: | |
Warning | |
H302, H410 | |
P264, P270, P273, P301+P312, P330, P391, P501 | |
NFPA 704 (fire diamond) |
3
0
0 |
Flash point | Non-flammable |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) |
140 mg/kg |
NIOSH (US health exposure limits): | |
PEL (Permissible) |
TWA 1 mg/m3 (as Cu) |
REL (Recommended) |
TWA 1 mg/m3 (as Cu) |
IDLH (Immediate danger) |
TWA 100 mg/m3 (as Cu) |
Safety data sheet (SDS) | JT Baker |
Related compounds | |
Other anions |
Copper(I) fluoride Copper(I) bromide Copper(I) iodide |
Other cations |
Silver(I) chloride Gold(I) chloride |
Related compounds |
Copper(II) chloride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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