Copper(I) iodide

Copper(I) iodide is the inorganic compound with the formula CuI. It is also known as cuprous iodide. It is useful in a variety of applications ranging from organic synthesis to cloud seeding.

Copper(I) iodide
Names
IUPAC name
Copper(I) iodide
Other names
Cuprous iodide, marshite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.028.795
PubChem CID
UNII
  • InChI=1S/Cu.HI/h;1H/q+1;/p-1 Y
    Key: LSXDOTMGLUJQCM-UHFFFAOYSA-M Y
  • InChI=1/Cu.HI/h;1H/q+1;/p-1
    Key: LSXDOTMGLUJQCM-REWHXWOFAV
SMILES
  • [Cu]I
Properties
CuI
Molar mass 190.45 g/mol
Appearance White solid
Odor odorless
Density 5.67 g/cm3
Melting point 606 °C (1,123 °F; 879 K)
Boiling point 1,290 °C (2,350 °F; 1,560 K) (decomposes)
0.000042 g/100 mL
Solubility product (Ksp)
1.27 x 10−12
Solubility soluble in ammonia and iodide solutions
insoluble in dilute acids
Vapor pressure 10 mm Hg (656 °C)
Magnetic susceptibility (χ)
-63.0·10−6 cm3/mol
Refractive index (nD)
2.346
Structure
zincblende
Tetrahedral anions and cations
Hazards
GHS labelling:
Danger
H302, H315, H319, H335, H410
P261, P273, P305+P351+P338, P501
NFPA 704 (fire diamond)
1
1
0
Flash point Non-flammable
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)
REL (Recommended)
TWA 1 mg/m3 (as Cu)
IDLH (Immediate danger)
TWA 100 mg/m3 (as Cu)
Safety data sheet (SDS) Sigma Aldrich
Related compounds
Other anions
Other cations
silver iodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Copper(I) iodide is white, but samples often appear tan or even, when found in nature as rare mineral marshite, reddish brown, but such color is due to the presence of impurities. It is common for samples of iodide-containing compounds to become discolored due to the facile aerobic oxidation of the iodide anion to molecular iodine.

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