Ammonia solution

Ammonia solution
Names
IUPAC name
Ammonium hydroxide
Other names
  • Ammonia water
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.014.225
EC Number
  • 215-647-6
E number E527 (acidity regulators, ...)
KEGG
PubChem CID
RTECS number
  • BQ9625000
UNII
UN number 2672
  • InChI=1S/H3N.H2O/h1H3;1H2 Y
    Key: VHUUQVKOLVNVRT-UHFFFAOYSA-N Y
  • InChI=1/H3N.H2O/h1H3;1H2
    Key: VHUUQVKOLVNVRT-UHFFFAOYAI
SMILES
  • [OH2].[NH3]
Properties
NH3(aq)
Molar mass 17.031 g/mol
Appearance Colourless liquid
Odor "Fishy", highly pungent
Density 0.91 g/cm3 (25 % w/w)
0.88 g/cm3 (35 % w/w)
Melting point −57.5 °C (−71.5 °F; 215.7 K) (25 % w/w)
−91.5 °C (35% w/w)
Boiling point 37.7 °C (99.9 °F; 310.8 K) (25 % w/w)
Miscible
Magnetic susceptibility (χ)
−31.5×10−6 cm3/mol
Thermochemistry
Std molar
entropy (S298)
111 J/(mol·K)
Std enthalpy of
formation fH298)
−80 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Moderately toxic
GHS labelling:
Danger
H302, H314, H335, H410
P261, P271, P273, P280, P303+P361+P353, P305+P351+P338
NFPA 704 (fire diamond)
3
1
0
COR
Lethal dose or concentration (LD, LC):
LD50 (median dose)
100 — 200 mg/kg
Safety data sheet (SDS) ICSC 0215 (10%-35% solution)
Related compounds
Other anions
Ammonium chloride
Ammonium cyanide
Other cations
Tetramethylammonium hydroxide
Related compounds
Ammonia
Hydroxylamine
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH3(aq). Although the name ammonium hydroxide suggests an alkali with the composition [NH+
4
][OH
]
, it is actually impossible to isolate samples of NH4OH. The ions NH+
4
and OH do not account for a significant fraction of the total amount of ammonia except in extremely dilute solutions.

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