Beryllium fluoride

Beryllium fluoride is the inorganic compound with the formula Be F2. This white solid is the principal precursor for the manufacture of beryllium metal. Its structure resembles that of quartz, but BeF2 is highly soluble in water.

Beryllium fluoride
Names
IUPAC name
Beryllium fluoride
Other names
Beryllium difluoride
Difluoroberyllane
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.029.198
PubChem CID
RTECS number
  • DS2800000
UNII
  • InChI=1S/Be.2FH/h;2*1H/q+2;;/p-2 Y
    Key: JZKFIPKXQBZXMW-UHFFFAOYSA-L Y
  • InChI=1/Be.2FH/h;2*1H/q+2;;/p-2
    Key: JZKFIPKXQBZXMW-NUQVWONBAD
SMILES
  • [Be+2].[F-].[F-]
Properties
BeF2
Molar mass 47.01 g/mol
hygroscopic
Appearance colorless, glassy lumps
Density 1.986 g/cm3
Melting point 554 °C (1,029 °F; 827 K)
Boiling point 1,169 °C (2,136 °F; 1,442 K)
very soluble
Solubility sparingly soluble in alcohol
Structure
Trigonal, α-quartz
Space group
P3121 (No. 152), Pearson symbol hP9
a = 473.29 pm, c = 517.88 pm
Molecular shape
Linear
Thermochemistry
1.102 J/K or 59 J/mol K
Std molar
entropy (S298)
45 J/mol K
Std enthalpy of
formation fH298)
-1028.2 kJ/g or -1010 kJ/mol
-941 kJ/mol
Hazards
GHS labelling:
Danger
H301, H305, H311, H314, H315, H319, H330, H335, H372, H411
P201, P202, P260, P264, P270, P271, P273, P280, P281, P284, P301+P310, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P312, P314, P320, P321, P322, P330, P361, P363, P391, P403+P233, P405, P501
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
90 mg/kg (oral, rat)
100 mg/kg (oral, mouse)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.002 mg/m3
C 0.005 mg/m3 (30 minutes), with a maximum peak of 0.025 mg/m3 (as Be)
REL (Recommended)
Ca C 0.0005 mg/m3 (as Be)
IDLH (Immediate danger)
Ca [4 mg/m3 (as Be)]
Safety data sheet (SDS) InChem MSDS
Related compounds
Other anions
Beryllium chloride
Beryllium bromide
Beryllium iodide
Other cations
Magnesium fluoride
Calcium fluoride
Strontium fluoride
Barium fluoride
Radium fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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