Beryllium bromide

Beryllium bromide is the chemical compound with the formula BeBr2. It is very hygroscopic and dissolves well in water. The compound is a polymer with tetrahedral coordinated Be centres.

Beryllium bromide
Names
IUPAC name
Beryllium bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.196
EC Number
  • 232-115-9
PubChem CID
UNII
  • InChI=1S/Be.2BrH/h;2*1H/q+2;;/p-2 Y
    Key: PBKYCFJFZMEFRS-UHFFFAOYSA-L Y
  • InChI=1/Be.2BrH/h;2*1H/q+2;;/p-2
    Key: PBKYCFJFZMEFRS-NUQVWONBAJ
SMILES
  • Br[Be-2](Br)([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1([Br+]1)[Br+][Be-2]1(Br)Br
Properties
BeBr2
Molar mass 168.820 g/mol
Appearance colorless white crystals
Density 3.465 g/cm3 (20 °C)
Melting point 508 °C (946 °F; 781 K)sublimes at 473 °C (883 °F; 746 K)
Boiling point 520 °C (968 °F; 793 K)
Highly
Solubility soluble in ethanol, diethyl ether, pyridine
insoluble in benzene
Structure
Orthorhombic
Thermochemistry
0.4111 J/g K
Std molar
entropy (S298)
9.5395 J/K
Std enthalpy of
formation fH298)
-2.094 kJ/g
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
see Berylliosis
GHS labelling:
Danger
H301, H315, H317, H319, H330, H335, H350i, H372, H411
P260, P301+P310, P304+P340, P305+P351+P338, P320, P330, P405, P501
NFPA 704 (fire diamond)
4
0
0
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.002 mg/m3
C 0.005 mg/m3 (30 minutes), with a maximum peak of 0.025 mg/m3 (as Be)
REL (Recommended)
Ca C 0.0005 mg/m3 (as Be)
IDLH (Immediate danger)
Ca [4 mg/m3 (as Be)]
Related compounds
Other anions
Beryllium fluoride
Beryllium chloride
Beryllium iodide
Other cations
Magnesium bromide
Calcium bromide
Strontium bromide
Barium bromide
Radium bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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