Carbon tetrafluoride
Tetrafluoromethane, also known as carbon tetrafluoride or R-14, is the simplest perfluorocarbon (CF4). As its IUPAC name indicates, tetrafluoromethane is the perfluorinated counterpart to the hydrocarbon methane. It can also be classified as a haloalkane or halomethane. Tetrafluoromethane is a useful refrigerant but also a potent greenhouse gas. It has a very high bond strength due to the nature of the carbon–fluorine bond.
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Names | |||
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IUPAC names
Tetrafluoromethane Carbon tetrafluoride | |||
Other names
Carbon tetrafluoride, Perfluoromethane, Tetrafluorocarbon, Freon 14, Halon 14, Arcton 0, CFC 14, PFC 14, R 14, UN 1982 | |||
Identifiers | |||
3D model (JSmol) |
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ChEBI | |||
ChemSpider | |||
ECHA InfoCard | 100.000.815 | ||
EC Number |
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PubChem CID |
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RTECS number |
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UNII | |||
CompTox Dashboard (EPA) |
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SMILES
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Properties | |||
CF4 | |||
Molar mass | 88.0043 g/mol | ||
Appearance | Colorless gas | ||
Odor | odorless | ||
Density | 3.72 g/L, gas (15 °C) | ||
Melting point | −183.6 °C (−298.5 °F; 89.5 K) | ||
Boiling point | −127.8 °C (−198.0 °F; 145.3 K) | ||
0.005%V at 20 °C 0.0038%V at 25 °C | |||
Solubility | soluble in benzene, chloroform | ||
Vapor pressure | 3.65 MPa at 15 °C 106.5 kPa at −127 °C | ||
Henry's law constant (kH) |
5.15 atm-cu m/mole | ||
Refractive index (nD) |
1.0004823 | ||
Viscosity | 17.32 μPa·s | ||
Structure | |||
Tetragonal | |||
Molecular shape |
Tetrahedral | ||
0 D | |||
Hazards | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards |
Simple asphyxiant and greenhouse gas | ||
NFPA 704 (fire diamond) |
1
0
0 SA | ||
Flash point | Non-flammable | ||
Safety data sheet (SDS) | ICSC 0575 | ||
Related compounds | |||
Other anions |
Tetrachloromethane Tetrabromomethane Tetraiodomethane | ||
Other cations |
Silicon tetrafluoride Germanium tetrafluoride Tin tetrafluoride Lead tetrafluoride | ||
Related fluoromethanes |
Fluoromethane Difluoromethane Fluoroform | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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