Lead(II) chloride

Lead(II) chloride (PbCl2) is an inorganic compound which is a white solid under ambient conditions. It is poorly soluble in water. Lead(II) chloride is one of the most important lead-based reagents. It also occurs naturally in the form of the mineral cotunnite.

Lead(II) chloride

The crystal structure of PbCl2, in the unconventional crystallographic setting Pnam. This corresponds to the standard Pnma setting by switching the labels on the b and c axes.
Names
IUPAC names
Lead(II) chloride
Lead dichloride
Other names
Plumbous chloride
Cotunnite
Dichloroplumbylene
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.028.950
EC Number
  • 231-845-5
PubChem CID
UNII
  • InChI=1S/2ClH.Pb/h2*1H;/q;;+2/p-2 Y
    Key: HWSZZLVAJGOAAY-UHFFFAOYSA-L Y
SMILES
  • Cl[Pb]Cl
Properties
PbCl2
Molar mass 278.10 g/mol
Appearance white odorless solid
Density 5.85 g/cm3
Melting point 501 °C (934 °F; 774 K)
Boiling point 950 °C (1,740 °F; 1,220 K)
0.99 g/100 mL (20 °C)
Solubility product (Ksp)
1.7×10−5 (20 °C)
Solubility slightly soluble in dilute HCl, ammonia;
insoluble in alcohol

Soluble in hot water as well as in presence of alkali hydroxide

Soluble in concentrated HCl (>6M)

Magnetic susceptibility (χ)
73.8·10−6 cm3/mol
Refractive index (nD)
2.199
Structure
Orthorhombic, oP12
Space group
Pnma (No. 62)
a = 762.040 pm, b = 453.420 pm, c = 904.520 pm
4
Thermochemistry
Std molar
entropy (S298)
135.98 JK−1mol−1
Std enthalpy of
formation fH298)
-359.41 kJ/mol
Hazards
GHS labelling:
Danger
H302, H332, H351, H360, H372, H410
P201, P261, P273, P304+P340, P308+P313, P312, P391
NFPA 704 (fire diamond)
3
0
0
Lethal dose or concentration (LD, LC):
LDLo (lowest published)
140 mg/kg (guinea pig, oral)
Related compounds
Other anions
Lead(II) fluoride
Lead(II) bromide
Lead(II) iodide
Other cations
Lead(IV) chloride
Tin(II) chloride
Germanium(II) chloride
Related compounds
Thallium(I) chloride
Bismuth chloride
Supplementary data page
Lead(II) chloride (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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