Hypophosphoric acid
Hypophosphoric acid is a mineral acid with the formula H4P2O6, with phosphorus in a formal oxidation state of +4. In the solid state it is present as the dihydrate, H4P2O6·2H2O. In hypophosphoric acid the phosphorus atoms are identical and joined directly with a P−P bond. Isohypophosphoric acid is a structural isomer of hypophosphoric acid in which one phosphorus has a hydrogen directedly bonded to it and that phosphorus atom is linked to the other one by an oxygen bridge to give a phosphorous acid/phosphoric acid mixed anhydride. The two phosphorus atoms are in the +3 and +5 oxidation states, respectively.
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IUPAC name
Hypodiphosphoric acid | |
Other names
Diphosphoric acid | |
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Properties | |
H4P2O6 | |
Molar mass | 161.98 g/mol |
Appearance | White solid (dihydrate) |
Melting point | 54 °C (129 °F; 327 K) |
Conjugate base | Hypophosphate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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