Dinitrogen difluoride
Dinitrogen difluoride is a chemical compound with the formula N2F2. It is a gas at room temperature, and was first identified in 1952 as the thermal decomposition product of the fluorine azide (FN3). It has the structure F−N=N−F and exists in both cis and trans isomers, as typical for diimides.
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Names | |||
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IUPAC name
cis- or trans-dinitrogen difluoride | |||
Other names
cis- or trans-difluorodiazene | |||
Identifiers | |||
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3D model (JSmol) |
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ChemSpider | |||
PubChem CID |
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SMILES
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Properties | |||
FN=NF | |||
Molar mass | 66.011 g·mol−1 | ||
Appearance | Colorless gas | ||
Density | 2.698 g/L | ||
Melting point | cis: less than −195 °C (−319.0 °F; 78.1 K) trans: −172 °C (−278 °F) | ||
Boiling point | cis: −105.75 °C (−158.35 °F; 167.40 K) trans: −111.45 °C (−168.61 °F) | ||
cis: 0.16 D trans: 0 D | |||
Thermochemistry | |||
Std enthalpy of formation (ΔfH⦵298) |
cis: 69.5 kJ/mol trans: 82.0 kJ/mol | ||
Related compounds | |||
Other anions |
Azide | ||
Other cations |
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Related compounds |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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