Diborane(2)

Diborane(2), also known as diborene, is an inorganic compound with the formula B2H2. The number 2 in diborane(2) indicates the number of hydrogen atoms bonded to the boron complex. There are other forms of diborane with different numbers of hydrogen atoms, including diborane(4) and diborane(6).

Diborane(2)
Names
IUPAC name
Diborene
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/B2H2/c1-2/h1-2H
    Key: HWGHUECIBSMKRW-UHFFFAOYSA-N
SMILES
  • B=B
Properties
B2H2
Molar mass 23.64 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Diborane(2) is a highly reactive molecule that rapidly decomposes, making it a challenge to study experimentally under ambient conditions. To observe diborane(2) experimentally, high-vacuum and low temperature conditions using matrix isolation techniques are required, such as trapping the molecule in inert matrices like neon or argon. As a result of these difficult synthesis conditions, its properties and behaviour have been predominantly studied using theoretical models and computational simulations.

Diborene also refers to a series of molecules with the formula R:(BH)=(BH):R or R-B=B-R where R is an organic group. Diborene derivatives are relatively stable and can be stored at room temperature under inert conditions. They have been synthesized and characterized experimentally, and have shown potential in a variety of applications.

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