Copper(II) fluoride
Copper(II) fluoride is an inorganic compound with the chemical formula CuF2. The anhydrous form is a white, ionic, crystalline, hygroscopic salt with a distorted rutile-type crystal structure, similar to other fluorides of chemical formulae MF2 (where M is a metal). The dihydrate, CuF2·2H2O, is blue in colour.
Unit cell of the anhydrous form | |
Ball-and-stick model of crystal packing in the anhydrous form | |
Dihydrate | |
Names | |
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IUPAC name
Copper difluoride | |
Other names
Cupric fluoride; Copper fluoride; Copper (2+) Difluoride | |
Identifiers | |
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3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.029.225 |
EC Number |
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PubChem CID |
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UNII |
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CompTox Dashboard (EPA) |
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SMILES
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Properties | |
CuF2 | |
Molar mass | 101.543 g/mol (anhydrous) 137.573 g/mol (dihydrate) |
Appearance | White crystalline powder When hydrated: Blue |
Density | 4.23 g/cm3 (anhydrous) 2.934 g/cm3 (dihydrate) |
Melting point | 836 °C (1,537 °F; 1,109 K) (anhydrous) 130 °C (dihydrate, decomposes) |
Boiling point | 1,676 °C (3,049 °F; 1,949 K) (anhydrous) |
Magnetic susceptibility (χ) |
+1050.0·10−6 cm3/mol |
Hazards | |
NIOSH (US health exposure limits): | |
PEL (Permissible) |
TWA 1 mg/m3 (as Cu) |
REL (Recommended) |
TWA 1 mg/m3 (as Cu) |
IDLH (Immediate danger) |
TWA 100 mg/m3 (as Cu) |
Related compounds | |
Other anions |
Copper(II) bromide Copper(II) chloride |
Other cations |
Silver(II) fluoride Cobalt(II) fluoride |
Related compounds |
Copper(I) fluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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