Chromium(III) chloride

Chromium(III) chloride (also called chromic chloride) is an inorganic chemical compound with the chemical formula CrCl3. It forms several hydrates with the formula CrCl3·nH2O, among which are hydrates where n can be 5 (chromium(III) chloride pentahydrate CrCl3·5H2O) or 6 (chromium(III) chloride hexahydrate CrCl3·6H2O). The anhydrous compound with the formula CrCl3 are violet crystals, while the most common form of the chromium(III) chloride are the dark green crystals of hexahydrate, CrCl3·6H2O. Chromium chlorides find use as catalysts and as precursors to dyes for wool.

Chromium(III) chloride

Anhydrous

Hexahydrate
Names
IUPAC name
  • Chromium(III) chloride
  • Chromium trichloride
Other names
Chromic chloride
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.030.023
1890 130477 532690
PubChem CID
RTECS number
  • GB5425000
UNII
  • InChI=1S/3ClH.Cr/h3*1H;/q;;;+3/p-3 Y
    Key: QSWDMMVNRMROPK-UHFFFAOYSA-K Y
  • InChI=1/3ClH.Cr/h3*1H;/q;;;+2/p-3
    Key: HUQISNLCWMVGCG-DFZHHIFOAJ
  • InChI=1/3ClH.Cr/h3*1H;/q;;;+3/p-3
    Key: QSWDMMVNRMROPK-DFZHHIFOAF
SMILES
  • Cl[Cr](Cl)Cl
Properties
CrCl3
Molar mass 158.36 g/mol (anhydrous)
266.45 g/mol (hexahydrate)
Appearance Purple (anhydrous), dark green (hexahydrate)
Density 2.87 g/cm3 (anhydrous)
1.760 g/cm3 (hexahydrate)
Melting point 1,152 °C (2,106 °F; 1,425 K) (anhydrous)
81 °C (hexahydrate)
Boiling point 1,300 °C (2,370 °F; 1,570 K) decomposes
slightly soluble (anhydrous)
585 g/L (hexahydrate)
Solubility insoluble in ethanol
insoluble in ether, acetone
Acidity (pKa) 2.4 (0.2M solution)
Magnetic susceptibility (χ)
+6890.0·10−6 cm3/mol
Structure
YCl3 structure
Octahedral
Hazards
GHS labelling:
Danger
H302, H314, H411
P260, P264, P270, P273, P280, P301+P312, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P330, P363, P391, P405, P501
NFPA 704 (fire diamond)
3
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
1870 mg/kg (oral, rat)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3
REL (Recommended)
TWA 0.5 mg/m3
IDLH (Immediate danger)
250 mg/m3
Safety data sheet (SDS) ICSC 1316 (anhydrous)
ICSC 1532 (hexahydrate)
Related compounds
Other anions
Other cations
  • Molybdenum(III) chloride
  • Tungsten(III) chloride
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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