Chromium(II) fluoride

Chromium(II) fluoride is an inorganic compound with the formula CrF2. It exists as a blue-green iridescent solid. Chromium(II) fluoride is sparingly soluble in water, almost insoluble in alcohol, and is soluble in boiling hydrochloric acid, but is not attacked by hot distilled sulfuric acid or nitric acid. Like other chromous compounds, chromium(II) fluoride is oxidized to chromium(III) oxide in air.

Chromium(II) fluoride

  Cr2+   F
Names
Other names
chromium difluoride, chromium fluouride, chromous fluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.140
EC Number
  • 233-168-0
PubChem CID
UNII
  • InChI=1S/Cr.2FH/h;2*1H/q+2;;/p-2
    Key: RNFYGEKNFJULJY-UHFFFAOYSA-L
SMILES
  • [F-].[F-].[Cr+2]
Properties
CrF2
Molar mass 89.9929 g·mol−1
Appearance blue-green iridescent crystals
hygroscopic, turns to Cr2O3 when heated in air
Density 3.79 g/cm3
Melting point 894 °C (1,641 °F; 1,167 K)
Boiling point > 1,300 °C (2,370 °F; 1,570 K)
76.7 g/100 mL
Structure
monoclinic
Thermochemistry
Std enthalpy of
formation fH298)
-8.645 kJ/g (solid)
Hazards
GHS labelling:
Danger
H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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