Benitoite

Benitoite (/bəˈntt/) is a rare blue barium titanium cyclosilicate mineral, found in hydrothermally altered serpentinite. It forms in low temperature, high pressure environments typical of subduction zones at convergent plate boundaries. Benitoite fluoresces under short wave ultraviolet light, appearing bright blue to bluish white in color. The more rarely seen clear to white benitoite crystals fluoresce red under long-wave UV light.

Benitoite
Benitoite on natrolite
General
CategoryCyclosilicate
Formula
(repeating unit)
BaTiSi3O9
IMA symbolBni
Strunz classification9.CA.05
Crystal systemHexagonal
Crystal classDitrigonal dipyramidal (6m2)
H-M symbol: (6 m2)
Space groupP6c2
Unit cella = 6.641, c = 9.7597(10) [Å]; Z = 2
Identification
ColorBlue, colorless
Crystal habitTabular dipyramidal crystals, granular
TwinningOn {0001} by rotation
Cleavage[1011] poor
FractureConchoidal
Mohs scale hardness6 - 6.5
LusterVitreous
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity3.65
Optical propertiesUniaxial (+)
Refractive indexnω = 1.756 - 1.757 nε = 1.802 - 1.804
Birefringenceδ = 0.046
PleochroismO = colorless; E = purple, indigo, greenish blue
Dispersion0.036–0.046
SolubilityInsoluble: HCl, H2SO4
Soluble: HF
Other characteristicsBlue fluorescence under SW UV; intense blue cathodoluminescence
References

It was discovered in 1907 by prospector James M. Couch in the San Benito Mountains roughly halfway between San Francisco and Los Angeles. Due to its similar color, Couch originally believed it to be sapphire, a variety of corundum. In 1909, a sample was sent to the University of California, Berkeley, where mineralogist Dr. George D. Louderback realized it was a previously unknown mineral. Corundum (sapphire) has a defined Mohs hardness of 9, while benitoite is much softer. He named it benitoite for its occurrence near the headwaters of the San Benito River in San Benito County, California.

Benitoite occurs in a number of isolated locations globally, but gemstone quality material has only been found in California at the Benito Gem Mine where it was first discovered. It has been correctly identified in Montana, Arkansas, Japan, and Australia although they formed under slightly different conditions and only grow large enough to be considered an accessory mineral. In 1985 benitoite was named as the official state gem of California.

Non-gem crystals of benitoite can have a very rare, six-pointed twinned form.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.