Antimony telluride

Antimony telluride is an inorganic compound with the chemical formula Sb2Te3. As is true of other pnictogen chalcogenide layered materials, it is a grey crystalline solid with layered structure. Layers consist of two atomic sheets of antimony and three atomic sheets of tellurium and are held together by weak van der Waals forces. Sb2Te3 is a narrow-gap semiconductor with a band gap 0.21 eV; it is also a topological insulator, and thus exhibits thickness-dependent physical properties.

Antimony telluride

Electron micrograph of a seamless Bi2Te3/Sb2Te3 heterojunction and its atomic model (blue: Bi, green: Sb, red: Te)
Names
Other names
antimony telluride, antimony(III) telluride, antimony telluride, diantimony tritelluride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.014.074
PubChem CID
  • InChI=1S/2Sb.3Te/q2*+3;3*-2 Y
    Key: RSPNQEPAQCYWKS-UHFFFAOYSA-N Y
  • InChI=1/2Sb.3Te/q2*+3;3*-2
    Key: RSPNQEPAQCYWKS-UHFFFAOYAT
SMILES
  • [Te]=[Sb][Te][Sb]=[Te]
  • [Sb+3].[Sb+3].[Te-2].[Te-2].[Te-2]
Properties
Sb2Te3
Molar mass 626.32 g·mol−1
Appearance grey solid
Density 6.50 g cm−3
Melting point 620 °C (1,148 °F; 893 K)
Band gap 0.21 eV
Thermal conductivity 1.65 W/(m·K) (308 K)
Structure
Rhombohedral, hR15
Space group
R3m, No. 166
a = 0.4262 nm, c = 3.0435 nm
3
Hazards
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.5 mg/m3 (as Sb)
REL (Recommended)
TWA 0.5 mg/m3 (as Sb)
Related compounds
Other anions
Sb2O3
Sb2S3
Sb2Se3
Other cations
As2Te3
Bi2Te3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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