Lanthanum(III) bromide

Lanthanum(III) bromide (LaBr3) is an inorganic halide salt of lanthanum. When pure, it is a colorless white powder. The single crystals of LaBr3 are hexagonal crystals with melting point of 783 °C. It is highly hygroscopic and water-soluble. There are several hydrates, La3Br·x H2O, of the salt also known. It is often used as a source of lanthanum in chemical synthesis and as a scintillation material in certain applications.

Lanthanum(III) bromide
Names
IUPAC names
Lanthanum(III) bromide
Lanthanum tribromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.527
EC Number
  • 236-896-7
PubChem CID
  • InChI=1S/3BrH.La/h3*1H;/q;;;+3/p-3 Y
    Key: XKUYOJZZLGFZTC-UHFFFAOYSA-K Y
  • InChI=1/3BrH.La/h3*1H;/q;;;+3/p-3
    Key: XKUYOJZZLGFZTC-DFZHHIFOAJ
SMILES
  • Br[La](Br)Br
Properties
LaBr3
Molar mass 378.62 g/mol (anhydrous)
Appearance white solid, hygroscopic
Density 5.06 g/cm3, solid
Melting point 783 °C (1,441 °F; 1,056 K)
Boiling point 1,577 °C (2,871 °F; 1,850 K)
Very soluble
Structure
hexagonal (UCl3 type), hP8
Space group
P63/m, No. 176
Tricapped trigonal prismatic
(nine-coordinate)
Hazards
GHS labelling:
Warning
H315, H319, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Flash point not flammable
Related compounds
Other anions
Lanthanum(III) fluoride
Lanthanum(III) chloride
Lanthanum(III) iodide
Other cations
Cerium(III) bromide
Praseodymium(III) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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