Lanthanite

Lanthanites are a group of isostructural rare earth element (REE) carbonate minerals. This group comprises the minerals lanthanite-(La), lanthanite-(Ce), and lanthanite-(Nd). This mineral group has the general chemical formula of (REE)2(CO3)3·8(H2O). Lanthanites include La, Ce, and Nd as major elements and often contain subordinate amounts of other REEs including praseodymium (Pr), samarium (Sm), europium (Eu) and dysprosium (Dy). The lanthanite crystal structure consists of layers of 10-fold coordinated REE-oxygen (O) polyhedra and carbonate (CO32−) groups connected by hydrogen bonds to interlayer water molecules, forming a highly hydrated structure.

Lanthanite-(La), Lanthanite-(Nd), Lanthanite-(Ce)
Lanthanite-(Nd) from Mitsukoshi, Hizen-cho, Karatsu City, Saga Prefecture, Japan.
General
CategoryCarbonate minerals
Formula
(repeating unit)
(REE)2(CO3)3·8(H2O)
IMA symbolLtn
Strunz classification5.CC.25
Dana classification(La): 15.04.02.01
(Nd): 15.04.02.02
(Ce): 15.04.02.03
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPbnb
Unit cella = 9.476(4)-9.483(6)
b = 16.940(8)-16.938(11)
c = 8.942(4)-8.965(3) [Å], Z = 4
Identification
ColorPale pink to purple
Crystal habitPlaty
TwinningCommon on {101}
CleavageMicaceous, perfect on {101}
FractureUneven
TenacitySectile
Mohs scale hardness2.5
LusterVitreous to pearly
StreakWhite
Density2.78-2.84 (measured), 2.79-2.816 (calculated)
Optical propertiesBiaxial (-)
2V angle58-61° (measured), 60-63.5° (calculated)
References
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