Jarosite

Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct during the purification and refining of zinc and is also commonly associated with acid mine drainage and acid sulfate soil environments.

Jarosite
Jarosite on quartz from the Arabia District, Pershing County, Nevada
General
CategorySulfate minerals
Formula
(repeating unit)
KFe3(SO4)2(OH)6
IMA symbolJrs
Strunz classification7.BC.10
Dana classification30.2.5.1
Crystal systemTrigonal
Crystal classRhombohedral (3m)
H-M symbol: (3m)
Space groupR3m
Unit cella = 7.304 Å, c = 17.268 Å; Z = 3
Identification
Formula mass500.8 g/mol
ColorAmber yellow or dark brown
Crystal habitCrystals are usually pseudocubic or tabular, also as granular crusts, nodules, fibrous masses or concretionary.
CleavageDistinct on {0001}
FractureUneven to conchoidal
TenacityBrittle
Mohs scale hardness2.5–3.5
LusterSubadamantine to vitreous, resinous on fractures
Streaklight yellow
DiaphaneityTransparent to translucent
Specific gravity2.9 to 3.3
Optical propertiesUniaxial (−), usually anomalously biaxial with very small 2V
Refractive indexnω = 1.815 to 1.820; nε = 1.713 to 1.715
Birefringence0.102 to 0.105
PleochroismE colorless, very pale yellow, or pale greenish yellow, O deep golden yellow or reddish brown
SolubilityInsoluble in water. Soluble in HCl.
Other characteristicsStrongly pyroelectric. Non-fluorescent. Barely detectable radioactivity
References
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