Iron(III) phosphate
Iron(III) phosphate, also ferric phosphate, is the inorganic compound with the formula FePO4. Four polymorphs of anhydrous FePO4 are known. Additionally two polymorphs of the dihydrate FePO4·(H2O)2 are known. These materials have attracted much interest as potential cathode materials in batteries.
Names | |
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IUPAC name
Iron(III) phosphate | |
Other names
Ferric orthophosphate, Ferric phosphate | |
Identifiers | |
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3D model (JSmol) |
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ChEBI | |
ChemSpider | |
ECHA InfoCard | 100.030.123 |
PubChem CID |
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UNII | |
CompTox Dashboard (EPA) |
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SMILES
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Properties | |
FePO4 | |
Molar mass | 150.815 g/mol (anhydrous) |
Appearance | yellow-brown solid |
Density | 3.056 g/cm3 (anhydrous) 2.87 g/cm3 (20 °C, dihydrate) |
Melting point | 250 °C (482 °F; 523 K) (dihydrate) decomposes |
anhydrous: insoluble dihydrate: 0.642 g/100 mL (100 °C) | |
Solubility product (Ksp) |
9.91×10−16 |
Magnetic susceptibility (χ) |
+11,500.0·10−6 cm3/mol |
Thermochemistry | |
Heat capacity (C) |
180.5 J/mol·K (dihydrate) |
Std molar entropy (S⦵298) |
171.3 J/mol·K (dihydrate) |
Std enthalpy of formation (ΔfH⦵298) |
-1888 kJ/mol (dihydrate) |
Hazards | |
GHS labelling: | |
Warning | |
H315, H319, H335 | |
P261, P305+P351+P338 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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