Iron(III) bromide

Iron(III) bromide is the chemical compound with the formula FeBr3. Also known as ferric bromide, this red-brown odorless compound is used as a Lewis acid catalyst in the halogenation of aromatic compounds. It dissolves in water to give acidic solutions.

Iron(III) bromide
Names
IUPAC name
Iron(III) bromide
Other names
Ferric bromide
Iron tribromide
tribromoiron
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.069
EC Number
  • 233-089-1
PubChem CID
UNII
  • InChI=1S/3BrH.Fe/h3*1H;/q;;;+3/p-3 Y
    Key: FEONEKOZSGPOFN-UHFFFAOYSA-K N
  • InChI=1/3BrH.Fe/h3*1H;/q;;;+3/p-3
    Key: FEONEKOZSGPOFN-DFZHHIFOAP
SMILES
  • [Fe](Br)(Br)Br
Properties
FeBr3
Molar mass 295.56 g mol−1
Appearance brown solid
Odor odorless
Density 4.50 g cm−3
Melting point 200 °C (392 °F; 473 K) (decomposes)
Structure
Trigonal, hR24
Space group
R-3, No. 148
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
corrosive
GHS labelling:
Warning
H315, H319, H335
NFPA 704 (fire diamond)
3
0
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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