Iron(II,III) sulfide

Iron(II,III) sulfide is a blue-black (sometimes pinkish) chemical compound of iron and sulfur with formula Fe3S4 or FeS·Fe2S3, which is much similar to iron(II,III) oxide. It occurs naturally as the sulfide mineral greigite and is magnetic. It is a bio-mineral produced by and found in magnetotactic bacteria. It is a mixed valence compound, featuring both Fe2+ and Fe3+ centers, in 1:2 ratio.

Iron(II,III) sulfide
Names
Other names
Ferrous-ferric sulfide, greigite
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
PubChem CID
  • InChI=1S/3Fe.4S/q+2;2*+3;4*-2
    Key: UHUWQCGPGPPDDT-UHFFFAOYSA-N
SMILES
  • [S-2].[S-2].[S-2].[S-2].[Fe+2].[Fe+3].[Fe+3]
Properties
FeS·Fe2S3
Molar mass 295.805
Appearance Bluish-black, pinkish
Density 4.049 g/cm3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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