Hexafluoropropylene oxide
Hexafluoropropylene oxide (HFPO) is an intermediate used in industrial organofluorine chemistry; specifically it is a monomer for fluoropolymers. This colourless gas is the epoxide of hexafluoropropylene, which is a fluorinated analog of propylene oxide, HFPO is produced by DuPont and 3M and as a precursor to the lubricant Krytox and related materials. It is generated by oxidation of perfluoropropylene, e.g. with oxygen as well as other oxidants.
Names | |
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IUPAC name
2,2,3-Trifluoro-3-(trifluoromethyl)oxirane | |
Other names
trifluoro(trifluoromethyl)oxirane | |
Identifiers | |
3D model (JSmol) |
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Abbreviations | HFPO |
ChemSpider | |
ECHA InfoCard | 100.006.411 |
PubChem CID |
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UNII | |
CompTox Dashboard (EPA) |
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SMILES
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Properties | |
C3F6O | |
Molar mass | 166.02 g/mol |
Appearance | colourless gas |
Density | 1300kg/m3 at 25 °C |
Melting point | −144 °C (−227 °F; 129 K) |
Boiling point | −27.4 °C (−17.3 °F; 245.8 K) |
Solubility | nonpolar solvents |
Vapor pressure | 660kPa at 25 °C |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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