Hexafluoropropylene oxide

Hexafluoropropylene oxide (HFPO) is an intermediate used in industrial organofluorine chemistry; specifically it is a monomer for fluoropolymers. This colourless gas is the epoxide of hexafluoropropylene, which is a fluorinated analog of propylene oxide, HFPO is produced by DuPont and 3M and as a precursor to the lubricant Krytox and related materials. It is generated by oxidation of perfluoropropylene, e.g. with oxygen as well as other oxidants.

Hexafluoropropylene oxide
Names
IUPAC name
2,2,3-Trifluoro-3-(trifluoromethyl)oxirane
Other names
trifluoro(trifluoromethyl)oxirane
Identifiers
3D model (JSmol)
Abbreviations HFPO
ChemSpider
ECHA InfoCard 100.006.411
PubChem CID
UNII
  • InChI=1S/C3F6O/c4-1(2(5,6)7)3(8,9)10-1 N
    Key: PGFXOWRDDHCDTE-UHFFFAOYSA-N N
  • InChI=1/C3F6O/c4-1(2(5,6)7)3(8,9)10-1
    Key: PGFXOWRDDHCDTE-UHFFFAOYAQ
SMILES
  • C1(C(O1)(F)F)(C(F)(F)F)F
  • FC(F)(F)C1(F)OC1(F)F
Properties
C3F6O
Molar mass 166.02 g/mol
Appearance colourless gas
Density 1300kg/m3 at 25 °C
Melting point −144 °C (−227 °F; 129 K)
Boiling point −27.4 °C (−17.3 °F; 245.8 K)
Solubility nonpolar solvents
Vapor pressure 660kPa at 25 °C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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