Gold(III) oxide

Gold(III) oxide (Au2O3) is an inorganic compound of gold and oxygen with the formula Au2O3. It is a red-brown solid that decomposes at 298 °C.

Gold(III) oxide
Names
IUPAC name
Gold(III) oxide
Other names
Gold trioxide, Gold sesquioxide, Auric oxide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.013.748
PubChem CID
UNII
  • InChI=1S/2Au.3O/q2*+3;3*-2
    Key: DDYSHSNGZNCTKB-UHFFFAOYSA-N
SMILES
  • [O-2].[O-2].[O-2].[Au+3].[Au+3]
Properties
Au2O3
Molar mass 441.93
Appearance red-brown solid
Density 11.34 g/cm3 at 20 °C
Melting point 298 °C (568 °F; 571 K)
insoluble in water, soluble in hydrochloric and nitric acid
Structure
Orthorhombic, oF40
Space group
Fdd2, No. 43
Hazards
NFPA 704 (fire diamond)
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

According to X-ray crystallography, Au2O3 features square planar gold centers with both 2- and 3-coordinated oxides. The four Au-O bond distances range from 193 to 207 picometers. The crystals can be prepared by heating amorphous hydrated gold(III) oxide with perchloric acid and an alkali metal perchlorate in a sealed quartz tube at a temperature of around 250 °C and a pressure of around 30 MPa.

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