Gold(III) oxide
Gold(III) oxide (Au2O3) is an inorganic compound of gold and oxygen with the formula Au2O3. It is a red-brown solid that decomposes at 298 °C.
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IUPAC name
Gold(III) oxide | |
Other names
Gold trioxide, Gold sesquioxide, Auric oxide | |
Identifiers | |
3D model (JSmol) |
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ECHA InfoCard | 100.013.748 |
PubChem CID |
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UNII | |
CompTox Dashboard (EPA) |
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SMILES
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Properties | |
Au2O3 | |
Molar mass | 441.93 |
Appearance | red-brown solid |
Density | 11.34 g/cm3 at 20 °C |
Melting point | 298 °C (568 °F; 571 K) |
insoluble in water, soluble in hydrochloric and nitric acid | |
Structure | |
Orthorhombic, oF40 | |
Space group |
Fdd2, No. 43 |
Hazards | |
NFPA 704 (fire diamond) |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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According to X-ray crystallography, Au2O3 features square planar gold centers with both 2- and 3-coordinated oxides. The four Au-O bond distances range from 193 to 207 picometers. The crystals can be prepared by heating amorphous hydrated gold(III) oxide with perchloric acid and an alkali metal perchlorate in a sealed quartz tube at a temperature of around 250 °C and a pressure of around 30 MPa.
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