Gold(I,III) chloride

Gold(I,III) chloride is a black solid with the chemical formula Au4Cl8. It is an example of a mixed valence compound as it contains gold in two different oxidation states; square-planar gold(III) and almost linear gold(I). The compound is photosensitive as well as air- and moisture-sensitive.

Gold(I,III) chloride
Names
Systematic IUPAC name
tetra-μ-chlorotetrachlorotetragold
Other names
Mixed gold chloride, Tetragold octachloride
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/4Au.4ClH.4Cl/h;;;;4*1H;;;;/q;;2*+2;;;;;;;;/p-4 N
    Key: NWBJVUUFMJPGPV-UHFFFAOYSA-J N
SMILES
  • Cl[Au]1(Cl)[Cl][Au][Cl][Au](Cl)(Cl)[Cl][Au][Cl]1
  • [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Au+].[Au+].[Au+3].[Au+3]
Properties
Au
4
Cl
8
Molar mass 1071.490 g mol−1
Appearance black crystals
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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