Gadolinium(III) oxide

Gadolinium(III) oxide (archaically gadolinia) is an inorganic compound with the formula Gd2O3. It is one of the most commonly available forms of the rare-earth element gadolinium, derivatives of which are potential contrast agents for magnetic resonance imaging.

Gadolinium(III) oxide
Names
Other names
gadolinium sesquioxide, gadolinium trioxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.861
EC Number
  • 235-060-9
PubChem CID
RTECS number
  • LW4790000
UNII
  • InChI=1S/2Gd.3O/q2*+3;3*-2 Y
    Key: CMIHHWBVHJVIGI-UHFFFAOYSA-N Y
  • InChI=1/2Gd.3O/q2*+3;3*-2
    Key: CMIHHWBVHJVIGI-UHFFFAOYAI
SMILES
  • [Gd+3].[Gd+3].[O-2].[O-2].[O-2]
Properties
Gd2O3
Molar mass 362.50 g/mol
Appearance white odorless powder
Density 7.07 g/cm3
Melting point 2,420 °C (4,390 °F; 2,690 K)
insoluble
Solubility product (Ksp)
1.8×10−23
Solubility soluble in acid
Magnetic susceptibility (χ)
+53,200·10−6 cm3/mol
Structure
cubic, cI80, Monoclinic
Space group
Ia-3, No. 206, C2/m, No. 12
Hazards
GHS labelling:
Warning
H319, H410
P264, P273, P280, P305+P351+P338, P337+P313, P391, P501
Safety data sheet (SDS) External MSDS
Related compounds
Other anions
Gadolinium(III) chloride
Other cations
Europium(III) oxide, Terbium(III) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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