Fulvene

Fulvene (pentafulvene) is a hydrocarbon with the formula (CH=CH)2C=CH2. It is a prototype of a cross-conjugated hydrocarbon. Fulvene is rarely encountered, but substituted derivatives (fulvenes) are numerous. They are mainly of interest as ligands and precursors to ligands in organometallic chemistry.

Fulvene
Names
Preferred IUPAC name
5-Methylidenecyclopenta-1,3-diene
Other names
Fulvene
5-Methylene-1,3-cyclopentadiene
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
PubChem CID
UNII
  • InChI=1S/C6H6/c1-6-4-2-3-5-6/h2-5H,1H2 Y
    Key: PGTKVMVZBBZCKQ-UHFFFAOYSA-N Y
  • InChI=1/C6H6/c1-6-4-2-3-5-6/h2-5H,1H2
    Key: PGTKVMVZBBZCKQ-UHFFFAOYAV
SMILES
  • C=C1\C=C/C=C1
Properties
C6H6
Molar mass 78.114 g·mol−1
Magnetic susceptibility (χ)
-42.9·10−6 cm3/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Fulvene is an isomer of benzene, which when irradiated at 237 to 254 nm forms small amounts of fulvene along with benzvalene.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.