Fluoral

Trifluoroacetaldehyde, trifluoroethanal, or fluoral, is a fluorinated derivative of acetaldehyde with the formula CF3CHO. It is a gas at room temperature. Fluoral is used to introduce trifluoromethyl groups into organic compounds. It is highly electrophilic and fluoral forms a hydrate CF3CH(OH)2 upon contact with water like other halogenated acetaldehydes. It is commonly used in form of ethyl hemiacetal (1-ethoxy-2,2,2-trifluoroethanol, CF3CH(OCH2CH3)(OH)) due to the aldehyde's high reactivity, including the tendency to polymerise.

Fluoral
Names
IUPAC name
Trifluoroethanal
Other names
Trifluoroacetaldehyde
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 200-914-1
  • hydrate: 207-006-4
PubChem CID
UNII
  • InChI=1S/C2HF3O/c3-2(4,5)1-6/h1H
    Key: JVTSHOJDBRTPHD-UHFFFAOYSA-N
  • hydrate: InChI=1S/C2H3F3O2/c3-2(4,5)1(6)7/h1,6-7H
    Key: VGJWVEYTYIBXIA-UHFFFAOYSA-N
SMILES
  • C(=O)C(F)(F)F
  • hydrate: OC(O)C(F)(F)F
Properties
CF3CHO
Molar mass 98.024 g·mol−1
Appearance gas, hydrate is colourless crystals
Melting point 66 °C (hydrate)
Boiling point –18 °C

104 °C (hydrate)

forms hydrate
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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