Fluor-liddicoatite

Fluor-liddicoatite is a rare member of the tourmaline group of minerals, elbaite subgroup, and the theoretical calcium endmember of the elbaite-fluor-liddicoatite series; the pure end-member has not yet been found in nature. Fluor-liddicoatite is indistinguishable from elbaite by X-ray diffraction techniques. It forms a series with elbaite and probably also with olenite. Liddiocoatite is currently a non-approved mineral name, but Aurisicchio et al. (1999) and Breaks et al. (2008) found OH-dominant species. Formulae are

  • Fluor-liddicoatite Ca(Li2Al)Al6(BO3)3Si6O18(OH)3F
  • Elbaite Na(Al1.5Li1.5)Al6(BO3)3Si6O18(OH)4
  • Olenite NaAl9B3Si6O27O3(OH)
Fluor-liddicoatite
Liddicoatite from the Ambesabora pegmatite, Madagascar. Photo Rob Lavinsky
General
CategoryCyclosilicate
Tourmaline Group
Formula
(repeating unit)
Ca(Li2Al)Al6(BO3)3Si6O18(OH)3F
IMA symbolFld
Strunz classification9.CK.05 (10 ed)
8/E.19-80 (8 ed)
Dana classification61.3.1.2
Crystal systemTrigonal
Crystal classDitrigonal pyramidal (3m)
(same H-M symbol)
Space groupR3m
Identification
Formula mass945.8 g/mol
ColorUsually smoky brown, but also pink, red, green, blue, or rarely white.
Crystal habitStout prismatic, with a curved convex trigonal outline
CleavagePoor or absent on {0001}
FractureUneven to conchoidal
TenacityBrittle
Mohs scale hardness7+12
LusterVitreous
StreakWhite to very light brown
DiaphaneityTransparent to translucent
Specific gravity3.02
Optical propertiesUniaxial (−)
Refractive indexNo = 1.637, Ne = 1.621
PleochroismStrong: O dark brown or pink, E light brown or pale pink
Other characteristicsNot fluorescent, not radioactive
References

Fluor-liddicoatite was named in 1977 after Richard T. Liddicoat (1918–2002) gemmologist and president of the Gemological Institute of America, who is well known for introducing the GIA diamond grading system in 1953.

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