Earlandite

Earlandite, [Ca3(C6H5O7)2(H2O)2]·2H2O, is the mineral form of calcium citrate tetrahydrate. It was first reported in 1936 and named after the English microscopist and oceanographer Arthur Earland FRSE. Earlandite occurs as warty fine-grained nodules ca. 1 mm in size in bottom sediments of the Weddell Sea, off Antarctica. Its crystal symmetry was first assigned as orthorhombic, then as monoclinic, and finally as triclinic.

Earlandite
General
CategoryOrganic minerals
Formula
(repeating unit)
[Ca3(C6H5O7)2(H2O)2]·2H2O
IMA symbolEar
Strunz classification10.AC.15
Crystal systemTriclinic
Space groupP1 (No. 2)
Unit cella = 5.9466(4), b = 10.2247(8)
c = 16.6496(13) [Å]; Z = 2
Identification
ColorWhite, pale yellow
Crystal habitNodular
StreakWhite
DiaphaneityTransparent
Specific gravity1.80–1.95 (measured), 2.00 (calculated)
Optical propertiesBiaxial (+)
Refractive indexnα = 1.515
nβ = 1.530
nγ = 1.580
Birefringenceδ = 0.065
2V angle60°
Diagnostic featuresFine-grained and wart-like nodule crystal habit
SolubilityInsoluble
References
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