Dipotassium cyclooctatetraenide

Dipotassium cyclooctatetraenide, sometimes abbreviated K2COT, is an organopotassium compound with the formula K2C8H8. It is a brown solid that is used as a precursor to cyclooctatetraenide complexes, such as uranocene (U(C8H8)2). Analogs of K2C8H8 are known with ring substituents, with different alkali metals, and with various complexants.

Dipotassium cyclooctatetraenide
Names
Preferred IUPAC name
Dipotassium cycloocatetraenediide
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/C8H8.2K/c1-2-4-6-8-7-5-3-1;;/h1-8H;;/q-2;2*+1/b2-1-,5-3-,8-6-;;
    Key: JEUFATMWOKTCQC-YGFQESQOSA-N
  • InChI=1/C8H8.2K/c1-2-4-6-8-7-5-3-1;;/h1-8H;;/q-2;2*+1/b2-1-,5-3-,8-6-;;
    Key: JEUFATMWOKTCQC-YGFQESQOBL
SMILES
  • [K+].c1=c[cH-]c=c[cH-]c=c1.[K+]
Properties
C8H8K2
Appearance beige solid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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