Dimethyl sulfide

Dimethyl sulfide (DMS) or methylthiomethane is an organosulfur compound with the formula (CH3)2S. The simplest thioether, it is a flammable liquid that boils at 37 °C (99 °F) and has a characteristic disagreeable odor. It is a component of the smell produced from cooking of certain vegetables, notably maize, cabbage, beetroot, and seafoods. It is also an indication of bacterial contamination in malt production and brewing. It is a breakdown product of dimethylsulfoniopropionate (DMSP), and is also produced by the bacterial metabolism of methanethiol.

Dimethyl sulfide

Space-filling model of the molecular structure
Names
Preferred IUPAC name
(Methylsulfanyl)methane
Other names
  • (Methylthio)methane
  • Dimethyl sulfide
  • Dimethyl thioether
Identifiers
3D model (JSmol)
3DMet
1696847
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.000.770
EC Number
  • 200-846-2
KEGG
MeSH dimethyl+sulfide
PubChem CID
RTECS number
  • PV5075000
UNII
UN number 1164
  • InChI=1S/C2H6S/c1-3-2/h1-2H3 Y
    Key: QMMFVYPAHWMCMS-UHFFFAOYSA-N Y
  • Key: QMMFVYPAHWMCMS-UHFFFAOYAH
SMILES
  • CSC
Properties
(CH3)2S
Molar mass 62.13 g·mol−1
Appearance Colourless liquid
Odor Stench: cabbage, sulfurous, unpleasant
Density 0.846 g·cm−3
Melting point −98 °C; −145 °F; 175 K
Boiling point 35 to 41 °C; 95 to 106 °F; 308 to 314 K
log P 0.977
Vapor pressure 53.7 kPa (at 20 °C)
Magnetic susceptibility (χ)
−44.9×10−6 cm3/mol
Refractive index (nD)
1.435
Thermochemistry
Std enthalpy of
formation fH298)
−63.9 to −66.9 kJ⋅mol−1
−2.1812 to −2.1818 MJ⋅mol−1
Hazards
GHS labelling:
Danger
H225, H315, H318, H335
P210, P261, P280, P305+P351+P338
Flash point −36 °C (−33 °F; 237 K)
206 °C (403 °F; 479 K)
Explosive limits 19.7%
Safety data sheet (SDS) osha.gov
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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