Diazomethane

Diazomethane is an organic chemical compound with the formula CH2N2, discovered by German chemist Hans von Pechmann in 1894. It is the simplest diazo compound. In the pure form at room temperature, it is an extremely sensitive explosive yellow gas; thus, it is almost universally used as a solution in diethyl ether. The compound is a popular methylating agent in the laboratory, but it is too hazardous to be employed on an industrial scale without special precautions. Use of diazomethane has been significantly reduced by the introduction of the safer and equivalent reagent trimethylsilyldiazomethane.

Diazomethane
Names
IUPAC name
Diazomethane
Other names
Azimethylene,
Azomethylene,
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.005.803
EC Number
  • 206-382-7
KEGG
PubChem CID
UNII
  • InChI=1S/CH2N2/c1-3-2/h1H2 Y
    Key: YXHKONLOYHBTNS-UHFFFAOYSA-N Y
  • InChI=1/CH2N2/c1-3-2/h1H2
    Key: YXHKONLOYHBTNS-UHFFFAOYAZ
SMILES
  • N#[N+]-[C-]
Properties
CH2N2
Molar mass 42.04 g/mol
Appearance Yellow gas
Odor musty
Density 1.4 (air=1)
Melting point −145 °C (−229 °F; 128 K)
Boiling point −23 °C (−9 °F; 250 K)
hydrolysis
Structure
Molecular shape
linear C=N=N
polar
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
toxic and explosive
GHS labelling:
Danger
H350
P201, P202, P281, P308+P313, P405, P501
NFPA 704 (fire diamond)
4
3
4
Lethal dose or concentration (LD, LC):
LC50 (median concentration)
175 ppm (cat, 10 min)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.2 ppm (0.4 mg/m3)
REL (Recommended)
TWA 0.2 ppm (0.4 mg/m3)
IDLH (Immediate danger)
2 ppm
Related compounds
Related functional groups;
compounds
R-N=N=N (azide),
R-N=N-R (azo);
R2CN2 R = Ph, tms, CF3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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