Cobalt(II,III) oxide

Cobalt(II,III) oxide is an inorganic compound with the formula Co3O4. It is one of two well characterized cobalt oxides. It is a black antiferromagnetic solid. As a mixed valence compound, its formula is sometimes written as CoIICoIII2O4 and sometimes as CoO•Co2O3.

Cobalt(II,III) oxide
Names
IUPAC name
cobalt(II) dicobalt(III) oxide
Other names
cobalt oxide, cobalt(II,III) oxide, cobaltosic oxide, tricobalt tetroxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.780
EC Number
  • 215-157-2
PubChem CID
RTECS number
  • GG2500000
UNII
  • InChI=1S/3Co.4O Y
    Key: LBFUKZWYPLNNJC-UHFFFAOYSA-N Y
  • InChI=1/3Co.4O/rCo2O3.CoO/c3-1-5-2-4;1-2
    Key: LBFUKZWYPLNNJC-PMPQCLQHAA
SMILES
  • [Co]=O.O=[Co]O[Co]=O
Properties
Co3O4

CoO.Co2O3

Molar mass 240.80 g/mol
Appearance black solid
Density 6.07 g/cm3
Melting point 895 °C (1,643 °F; 1,168 K)
Boiling point 900 °C (1,650 °F; 1,170 K) (decomposes)
Insoluble
Solubility soluble (with degradation) in acids and alkalis
Magnetic susceptibility (χ)
+7380·10−6 cm3/mol
Structure
cubic
Space group
Fd3m, No. 227
Hazards
GHS labelling:
Danger
H317, H334, H350, H411
P261, P273, P284, P304+P340, P342+P311
NFPA 704 (fire diamond)
2
0
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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