Clinohumite

Clinohumite is an uncommon member of the humite group, a magnesium silicate according to the chemical formula (Mg, Fe)9(SiO4)4(F,OH)2. The formula can be thought of as four olivine (Mg2SiO4), plus one brucite (Mg(OH)2). Indeed, the mineral is essentially a hydrated olivine and occurs in altered ultramafic rocks and carbonatites. Most commonly found as tiny indistinct grains, large euhedral clinohumite crystals are sought by collectors and occasionally fashioned into bright, yellow-orange gemstones. Only two sources of gem-quality material are known: the Pamir Mountains of Tajikistan, and the Taymyr region of northern Siberia. It is one of two humite group minerals that have been cut into gems, the other being the much more common chondrodite.

Clinohumite
General
CategoryNesosilicate
Formula
(repeating unit)
(Mg,Fe)9(SiO4)4(F,OH)2
IMA symbolChu
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/c
Unit cella = 13.71 Å, b = 4.75 Å,
c = 10.29 Å; β = 100.83°; Z = 2
Identification
ColorBrownish to orange, yellow, red
Crystal habitGranular, prismatic, twinned
TwinningSimple, lamellar common on {100}
CleavagePoor on {100}
FractureSubconchoidal to uneven
Mohs scale hardness6
LusterVitreous to resinous
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity3.17–3.35
Optical propertiesbiaxial (+)
Refractive indexnα = 1.623 – 1.702 nβ = 1.636 – 1.709 nγ = 1.651 – 1.728
Birefringence+0.028
PleochroismX = golden yellow, yellow-brown, deep reddish yellow; Y = pale yellow, yellow-orange, light yellow; Z = pale yellow, yellow-orange, colorless
2V angleMeasured: 52° to 90°
References
Major varieties
TitanclinohumiteTitanoan; (Mg,Fe2+,Ti)9
[(F,OH,O)2|(SiO4)4]
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