Carbonyl fluoride
Carbonyl fluoride is a chemical compound with the formula COF2. It is a carbon oxohalide. This gas, like its analog phosgene, is colourless and highly toxic. The molecule is planar with C2v symmetry, bond lengths of 1.174 Å (C=O) and 1.312 Å (C–F), and an F–C–F bond angle of 108.0°.
| |||
Names | |||
---|---|---|---|
Preferred IUPAC name
Carbonyl difluoride | |||
Other names
| |||
Identifiers | |||
3D model (JSmol) |
|||
ChemSpider | |||
ECHA InfoCard | 100.005.941 | ||
EC Number |
| ||
PubChem CID |
|||
RTECS number |
| ||
UNII | |||
UN number | 2417 | ||
CompTox Dashboard (EPA) |
|||
| |||
SMILES
| |||
Properties | |||
COF2 | |||
Molar mass | 66.007 g·mol−1 | ||
Appearance | Colorless gas | ||
Odor | Pungent and very irritating | ||
Density | 2.698 g/L (gas), 1.139 g/cm3 (liquid at melting point) | ||
Melting point | −111.26 °C (−168.27 °F; 161.89 K) | ||
Boiling point | −84.57 °C (−120.23 °F; 188.58 K) | ||
Reacts | |||
Vapor pressure | 55.4 atm (20°C) | ||
Structure | |||
Molecular shape |
C2v | ||
0.95 D | |||
Hazards | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards |
Very toxic, reacts with water to release HF | ||
GHS labelling: | |||
Danger | |||
H280, H290, H314, H330, H331, H370 | |||
P234, P260, P261, P264, P270, P271, P280, P284, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P307+P311, P310, P311, P320, P321, P363, P390, P403+P233, P404, P405, P410+P403, P501 | |||
NFPA 704 (fire diamond) |
4
0
2 W | ||
Flash point | Non-flammable | ||
NIOSH (US health exposure limits): | |||
PEL (Permissible) |
none | ||
REL (Recommended) |
TWA 2 ppm (5 mg/m3) ST 5 ppm (15 mg/m3) | ||
IDLH (Immediate danger) |
N.D. | ||
Related compounds | |||
Related compounds |
| ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.