Bromine trifluoride

Bromine trifluoride is an interhalogen compound with the formula BrF3. At room temperature, it is a straw-coloured liquid with a pungent odor which decomposes violently on contact with water and organic compounds. It is a powerful fluorinating agent and an ionizing inorganic solvent. It is used to produce uranium hexafluoride (UF6) in the processing and reprocessing of nuclear fuel.

Bromine trifluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.211
EC Number
  • 232-132-1
PubChem CID
UNII
UN number 1746
  • InChI=1S/BrF3/c2-1(3)4
    Key: FQFKTKUFHWNTBN-UHFFFAOYSA-N
SMILES
  • FBr(F)F
Properties
BrF3
Molar mass 136.90 g/mol
Appearance straw-coloured liquid
hygroscopic
Odor Choking, pungent
Density 2.803 g/cm3
Melting point 8.77 °C (47.79 °F; 281.92 K)
Boiling point 125.72 °C (258.30 °F; 398.87 K)
Reacts with water
Structure
Molecular shape
T-shaped (C2v)
1.19 D
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Reacts violently with water to release HF, highly toxic, corrosive, powerful oxidizer
GHS labelling:
Danger
H271, H300+H310+H330, H314, H373
P102, P103, P210, P220, P221, P260, P264, P271, P280, P283, P284, P301+P310, P301+P330+P331, P303+P361+P353, P304+P312, P305+P351+P338+P310, P306+P360, P308+P313, P340, P363, P370+P380
NFPA 704 (fire diamond)
4
0
4
W
OX
Safety data sheet (SDS) http://www.chammascutters.com/en/downloads/Bromine-Trifluoride-MSDS.pdf
Related compounds
Other anions
Bromine monochloride
Other cations
Chlorine trifluoride
Iodine trifluoride
Related compounds
Bromine monofluoride
Bromine pentafluoride
Supplementary data page
Bromine trifluoride (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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