Boric acid

Orthoboric acid
Names
IUPAC name
Boric acid
Other names
Orthoboric acid, Boracic acid, Sassolite, Borofax, Trihydroxyborane, Boranetriol, Hydrogen borate, Acidum boricum
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.030.114
EC Number
  • 233-139-2
E number E284 (preservatives)
KEGG
PubChem CID
UNII
  • InChI=1S/BH3O3/c2-1(3)4/h2-4H Y
    Key: KGBXLFKZBHKPEV-UHFFFAOYSA-N Y
  • InChI=1/BH3O3/c2-1(3)4/h2-4H
    Key: KGBXLFKZBHKPEV-UHFFFAOYAI
SMILES
  • OB(O)O
  • [OH+]=[B-](O)O
Properties
BH3O3
Molar mass 61.83 g·mol−1
Appearance White crystalline solid
Density 1.435 g/cm3
Melting point 170.9 °C (339.6 °F; 444.0 K)
Boiling point 300 °C (572 °F; 573 K)
2.52 g/100 mL (0 °C)
4.72 g/100 mL (20 °C)
5.7 g/100 mL (25 °C)
19.10 g/100 mL (80 °C)
27.53 g/100 mL (100 °C)
Solubility in other solvents Soluble in lower alcohols
moderately soluble in pyridine
very slightly soluble in acetone
log P -0.29
Acidity (pKa) 9.24 (first proton), 12.4 (second), 13.3 (complete)
Conjugate base Borate
Magnetic susceptibility (χ)
-34.1·10−6 cm3/mol
Structure
Molecular shape
Trigonal planar
0 D
Pharmacology
S02AA03 (WHO) D08AD (WHO)
Hazards
GHS labelling:
NFPA 704 (fire diamond)
1
0
0
Flash point Nonflammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
2660 mg/kg, oral (rat)
Related compounds
Related compounds
Boron trioxide
Borax
Supplementary data page
Boric acid (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Boric acid, more specifically orthoboric acid, is a compound of boron, oxygen, and hydrogen with formula B(OH)3. It may also be called hydrogen orthoborate, trihydroxidoboron or boracic acid. It is usually encountered as colorless crystals or a white powder, that dissolves in water, and occurs in nature as the mineral sassolite. It is a weak acid that yields various borate anions and salts, and can react with alcohols to form borate esters.

Boric acid is often used as an antiseptic, insecticide, flame retardant, neutron absorber, or precursor to other boron compounds.

The term "boric acid" is also used generically for any oxoacid of boron, such as metaboric acid HBO2 and tetraboric acid H2B4O7.

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