Bismuth oxychloride

Bismuth oxychloride is an inorganic compound of bismuth with the formula BiOCl. It is a lustrous white solid used since antiquity, notably in ancient Egypt. Light wave interference from its plate-like structure gives a pearly iridescent light reflectivity similar to nacre. Previously, until the last decade of the twentieth century, bismuth oxochloride was known as bismuthyl chloride. It is also known as pigment pearl white.

Bismuth oxychloride
Names
Other names
bismuthyl chloride
bismuth oxochloride
bismuth oxide chloride
bismuth(III) oxide chloride
bismoclite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.202
EC Number
  • 232-122-7
PubChem CID
UNII
  • InChI=1S/Bi.ClH.O/h;1H;/q+1;;/p-1 Y
    Key: GLQBXSIPUULYOG-UHFFFAOYSA-M Y
  • InChI=1/Bi.ClH.O/h;1H;/q+1;;/p-1/rBiClO/c2-1-3
    Key: GLQBXSIPUULYOG-JKOFJLRAAJ
SMILES
  • Cl[Bi]=O
Properties
BiOCl
Molar mass 260.43 g·mol−1
Appearance Lustrous white crystals with a pearly iridescent light reflectivity
Density
  • 7.36 g/cm3 (measured)
  • 7.78 g/cm3 (calculated)
negligible
Solubility soluble in acids
Structure
Tetragonal, tP6
Space group
P4/nmm, No. 129
a = 0.3887 nm, c = 0.7354 nm
Hazards
GHS labelling:
Warning
H315, H319, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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