Barton–Kellogg reaction
The Barton–Kellogg reaction is a coupling reaction between a diazo compound and a thioketone, giving an alkene by way of an episulfide intermediate. The Barton–Kellogg reaction is also known as Barton–Kellogg olefination and Barton olefin synthesis.
| Barton–Kellogg reaction | |
|---|---|
| Named after | Sir Derek Barton Richard M. Kellogg |
| Reaction type | Coupling reaction |
| Identifiers | |
| RSC ontology ID | RXNO:0000495 |
This reaction was pioneered by Hermann Staudinger, and also goes by the name Staudinger type diazo-thioketone coupling.
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