Arsenic acid

Arsenic acid or arsoric acid is the chemical compound with the formula H3AsO4. More descriptively written as AsO(OH)3, this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic acid as such has not been isolated, but is only found in solution, where it is largely ionized. Its hemihydrate form (2H3AsO4·H2O) does form stable crystals. Crystalline samples dehydrate with condensation at 100 °C.

Arsenic acid
Names
IUPAC name
Arsoric acid
Other names
  • Desiccant L-10
  • Orthoarsenic acid
  • Trihydrogen arsenate
  • Zotox
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.029.001
EC Number
  • 231-901-9
KEGG
PubChem CID
RTECS number
  • CG0700000
UNII
UN number 1553, 1554
  • InChI=1S/AsH3O4/c2-1(3,4)5/h(H3,2,3,4,5) Y
    Key: DJHGAFSJWGLOIV-UHFFFAOYSA-N Y
  • InChI=1/AsH3O4/c2-1(3,4)5/h(H3,2,3,4,5)
    Key: DJHGAFSJWGLOIV-UHFFFAOYAY
SMILES
  • O[As+](O)([O-])O
Properties
H3AsO4
Molar mass 141.942 g·mol−1
Appearance White translucent or colorless crystals, hygroscopic
Density 2.5 g/cm3
Melting point 35.5 °C (95.9 °F; 308.6 K)
Boiling point 120 °C (248 °F; 393 K) decomposes
16.7 g/(100 mL)
Solubility soluble in ethanol
Vapor pressure 55 hPa (50 °C)
Acidity (pKa) pKa1 = 2.19
pKa2 = 6.94
pKa3 = 11.5
Conjugate base Arsenate
Structure
Molecular shape
Tetrahedral at arsenic atom
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Extremely toxic, carcinogenic, corrosive
GHS labelling:
Danger
H301, H312, H314, H331, H350, H361, H410
P201, P202, P260, P261, P264, P270, P271, P273, P280, P281, P301+P310, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P311, P312, P321, P322, P330, P363, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
4
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
48 mg/kg (rat, oral)

6 mg/kg (rabbit, oral)

Related compounds
Other cations
Sodium arsenate
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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