Ammonium tetrathiomolybdate
Ammonium tetrathiomolybdate is the chemical compound with the formula (NH4)2MoS4. This bright red ammonium salt is an important reagent in the chemistry of molybdenum and has been used as a building block in bioinorganic chemistry. The thiometallate (see metallate) anion has the distinctive property of undergoing oxidation at the sulfur centers concomitant with reduction of the metal from Mo(VI) to Mo(IV).
Names | |
---|---|
Other names
ammonium thiomolybdate | |
Identifiers | |
3D model (JSmol) |
|
ChemSpider | |
ECHA InfoCard | 100.167.865 |
PubChem CID |
|
RTECS number |
|
UNII | |
CompTox Dashboard (EPA) |
|
| |
SMILES
| |
Properties | |
(NH4)2MoS4 | |
Molar mass | 260.28 g/mol |
Appearance | red crystals |
Melting point | decomp ~ 155 °C |
Basicity (pKb) | decomposes |
Structure | |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards |
toxic |
GHS labelling: | |
Warning | |
H315, H319, H335 | |
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501 | |
Related compounds | |
Related compounds |
(NH4)2[WS4], MoS2 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.