Ammonium tetrathiomolybdate

Ammonium tetrathiomolybdate is the chemical compound with the formula (NH4)2MoS4. This bright red ammonium salt is an important reagent in the chemistry of molybdenum and has been used as a building block in bioinorganic chemistry. The thiometallate (see metallate) anion has the distinctive property of undergoing oxidation at the sulfur centers concomitant with reduction of the metal from Mo(VI) to Mo(IV).

Ammonium tetrathiomolybdate
Names
Other names
ammonium thiomolybdate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.167.865
PubChem CID
RTECS number
  • QA4668250
UNII
  • InChI=1S/Mo.2H3N.4S/h;2*1H3;;;;/q;;;;;2*-1/p+2 Y
    Key: PQNOIAHNKHBLRN-UHFFFAOYSA-P Y
  • InChI=1S/Mo.2H3N.4S/h;2*1H3;;;;/q;;;;;2*-1/p+2
  • Key: PQNOIAHNKHBLRN-UHFFFAOYSA-P
SMILES
  • [NH4+].[NH4+].[S-][Mo]([S-])(=S)=S
Properties
(NH4)2MoS4
Molar mass 260.28 g/mol
Appearance red crystals
Melting point decomp ~ 155 °C
Basicity (pKb) decomposes
Structure
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
toxic
GHS labelling:
Warning
H315, H319, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Related compounds
Related compounds
(NH4)2[WS4],
MoS2
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.