Ammonium perrhenate

Ammonium perrhenate (APR) is the ammonium salt of perrhenic acid, NH4ReO4. It is the most common form in which rhenium is traded. It is a white salt; soluble in ethanol and water, and mildly soluble in NH4Cl. It was first described soon after the discovery of rhenium.

Ammonium perrhenate
Names
Other names
Ammonium perrhenate,
Ammonium perrhenate(VII)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.690
EC Number
  • 237-075-6
PubChem CID
  • InChI=1S/H3N.4O.Re/h1H3;;;;;/q;;;;-1;/p+1 Y
    Key: HOJYZCWLNWENHS-UHFFFAOYSA-O Y
  • InChI=1/H3N.4O.Re/h1H3;;;;;/q;;;;-1;/p+1/rH3N.O4Re/c;1-5(2,3)4/h1H3;/q;-1/p+1
    Key: HOJYZCWLNWENHS-WUACXKGRAA
SMILES
  • [O-] [Re](=O)(=O)=O.[NH4+]
Properties
NH4ReO4
Molar mass 268.2359 g/mol
Density 3.97 g/cm3, solid
Melting point 200°C (decomposes)
2.8 g/100 mL (0 °C), 6.2 g/100 mL (20 °C), 12.0 g/100 mL (40 °C), 20.7 g/100 mL (60 °C), 32.3 g/100 mL (80 °C), 39.1 g/100 mL (90 °C)
Structure
scheelite
N/A
Hazards
Flash point Non-flammable
Related compounds
Other anions
Ammonium permanganate; ammonium pertechnetate
Other cations
Sodium perrhenate; perrhenic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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