Ammonium nitrate

Ammonium nitrate
Names
IUPAC name
Ammonium nitrate
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.026.680
EC Number
  • 229-347-8
PubChem CID
RTECS number
  • BR9050000
UNII
UN number 0222 – with > 0.2% combustible substances
1942 – with ≤ 0.2% combustible substances
2067 – fertilizers
2426 – liquid
  • InChI=1S/NO3.H3N/c2-1(3)4;/h;1H3/q-1;/p+1 Y
    Key: DVARTQFDIMZBAA-UHFFFAOYSA-O Y
  • InChI=1/NO3.H3N/c2-1(3)4;/h;1H3/q-1;/p+1
    Key: DVARTQFDIMZBAA-IKLDFBCSAH
SMILES
  • [O-][N+]([O-])=O.[NH4+]
Properties
NH4NO3
Molar mass 80.043 g/mol
Appearance white crystalline solid
Density 1.725 g/cm3 (20 °C)
Melting point 169.6 °C (337.3 °F; 442.8 K)
Boiling point approx. 210 °C (410 °F; 483 K) decomposes
Endothermic
118 g/100 ml (0 °C)
150 g/100 ml (10 °C)
192 g/100 ml (20 °C)
297 g/100 ml (40 °C)
410 g/100 ml (60 °C)
576 g/100 ml (80 °C)
1024 g/100 ml (100 °C)
Magnetic susceptibility (χ)
−33.6×10−6 cm3/mol
Structure
orthorhombic
Explosive data
Shock sensitivity very low
Friction sensitivity very low
Detonation velocity 2500 m/s
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Explosive, Oxidizer
GHS labelling:
Danger
H201, H271, H319
P220, P221, P264, P271, P280, P372
NFPA 704 (fire diamond)
1
0
3
OX
Lethal dose or concentration (LD, LC):
LD50 (median dose)
2085–5300 mg/kg (oral in rats, mice)
Related compounds
Other anions
Ammonium nitrite
Other cations
Sodium nitrate
Potassium nitrate
Hydroxylammonium nitrate
Related compounds
Ammonium perchlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Ammonium nitrate is a chemical compound with the formula NH4NO3. It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is predominantly used in agriculture as a high-nitrogen fertilizer.

Its other major use is as a component of explosive mixtures used in mining, quarrying, and civil construction. It is the major constituent of ANFO, a popular industrial explosive which accounts for 80% of explosives used in North America; similar formulations have been used in improvised explosive devices.

Many countries are phasing out its use in consumer applications due to concerns over its potential for misuse. Accidental ammonium nitrate explosions have killed thousands of people since the early 20th century. Global production was estimated at 21.6 million tonnes in 2017. By 2021, global production of ammonium nitrate was down to 16.7 million tonnes.

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