Ammonium dichromate

Ammonium dichromate is an inorganic compound with the formula (NH4)2Cr2O7. In this compound, as in all chromates and dichromates, chromium is in a +6 oxidation state, commonly known as hexavalent chromium. It is a salt consisting of ammonium ions and dichromate ions.

Ammonium dichromate
Names
IUPAC name
Ammonium dichromate
Other names
Ammonium bichromate
Ammonium pyrochromate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.221
PubChem CID
RTECS number
  • HX7650000
UNII
UN number 1439
  • InChI=1S/2Cr.2H3N.7O/h;;2*1H3;;;;;;;/q;;;;;;;;;2*-1/p+2 Y
    Key: JOSWYUNQBRPBDN-UHFFFAOYSA-P Y
  • InChI=1/2Cr.2H3N.7O/h;;2*1H3;;;;;;;/q;;;;;;;;;2*-1/p+2/rCr2O7.2H3N/c3-1(4,5)9-2(6,7)8;;/h;2*1H3/q-2;;/p+2
    Key: JOSWYUNQBRPBDN-RFRSXZKWAS
SMILES
  • [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O.[NH4+].[NH4+]
Properties
(NH4)2Cr2O7
Molar mass 252.07 g/mol
Appearance Orange-red crystals
Odor odorless
Density 2.115 g/cm3
Melting point 180 °C (356 °F; 453 K) decomposes
18.2 g/100 ml (0 °C)
35.6 g/100 ml (20 °C)
40 g/100 ml (25 °C)
156 g/100 ml (100 °C)
Solubility insoluble in acetone
soluble in ethanol
Structure
monoclinic
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Very toxic, explosive, oxidizing, carcinogenic, mutagenic, dangerous for the environment
GHS labelling:
H272, H301, H312, H314, H317, H330, H334, H340, H350, H360, H372, H410
P201, P220, P260, P273, P280, P284
NFPA 704 (fire diamond)
4
2
3
OX
190 °C (374 °F; 463 K)
Lethal dose or concentration (LD, LC):
LD50 (median dose)
20–250 mg/kg
Safety data sheet (SDS) ICSC 1368
Related compounds
Other cations
Potassium dichromate
Sodium dichromate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Ammonium dichromate is sometimes known as Vesuvian Fire, because of its use in demonstrations of tabletop "volcanoes". However, this demonstration has become unpopular in schools due to the compound's carcinogenic nature. It has also been used in pyrotechnics and in the early days of photography.

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