Ammonium dichromate
Ammonium dichromate is an inorganic compound with the formula (NH4)2Cr2O7. In this compound, as in all chromates and dichromates, chromium is in a +6 oxidation state, commonly known as hexavalent chromium. It is a salt consisting of ammonium ions and dichromate ions.
Names | |
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IUPAC name
Ammonium dichromate | |
Other names
Ammonium bichromate Ammonium pyrochromate | |
Identifiers | |
3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.029.221 |
PubChem CID |
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RTECS number |
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UNII | |
UN number | 1439 |
CompTox Dashboard (EPA) |
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SMILES
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Properties | |
(NH4)2Cr2O7 | |
Molar mass | 252.07 g/mol |
Appearance | Orange-red crystals |
Odor | odorless |
Density | 2.115 g/cm3 |
Melting point | 180 °C (356 °F; 453 K) decomposes |
18.2 g/100 ml (0 °C) 35.6 g/100 ml (20 °C) 40 g/100 ml (25 °C) 156 g/100 ml (100 °C) | |
Solubility | insoluble in acetone soluble in ethanol |
Structure | |
monoclinic | |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards |
Very toxic, explosive, oxidizing, carcinogenic, mutagenic, dangerous for the environment |
GHS labelling: | |
H272, H301, H312, H314, H317, H330, H334, H340, H350, H360, H372, H410 | |
P201, P220, P260, P273, P280, P284 | |
NFPA 704 (fire diamond) |
4
2
3 OX |
190 °C (374 °F; 463 K) | |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) |
20–250 mg/kg |
Safety data sheet (SDS) | ICSC 1368 |
Related compounds | |
Other cations |
Potassium dichromate Sodium dichromate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
Ammonium dichromate is sometimes known as Vesuvian Fire, because of its use in demonstrations of tabletop "volcanoes". However, this demonstration has become unpopular in schools due to the compound's carcinogenic nature. It has also been used in pyrotechnics and in the early days of photography.
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