Aluminium sulfide
Aluminium sulfide is a chemical compound with the formula Al2S3. This colorless species has an interesting structural chemistry, existing in several forms. The material is sensitive to moisture, hydrolyzing to hydrated aluminum oxides/hydroxides. This can begin when the sulfide is exposed to the atmosphere. The hydrolysis reaction generates gaseous hydrogen sulfide (H2S).
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Other names
Aluminium sulfide | |
Identifiers | |
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ChemSpider | |
ECHA InfoCard | 100.013.736 |
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Properties | |
Al2S3 | |
Molar mass | 150.158 g/mol |
Appearance | gray solid |
Density | 2.02 g/cm3 |
Melting point | 1,100 °C (2,010 °F; 1,370 K) |
Boiling point | 1,500 °C (2,730 °F; 1,770 K) sublimes |
decomposes | |
Solubility | insoluble in acetone |
Structure | |
trigonal | |
Thermochemistry | |
Heat capacity (C) |
105.1 J/mol K |
Std molar entropy (S⦵298) |
116.9 J/mol K |
Std enthalpy of formation (ΔfH⦵298) |
-724 kJ/mol |
Hazards | |
GHS labelling: | |
Danger | |
NFPA 704 (fire diamond) |
4
0
2 W |
Safety data sheet (SDS) | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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