Alstonite

Alstonite, also known as bromlite, is a low temperature hydrothermal mineral that is a rare double carbonate of calcium and barium with the formula BaCa(CO
3
)
2
, sometimes with some strontium. Barytocalcite and paralstonite have the same formula but different structures, so these three minerals are said to be trimorphous. Alstonite is triclinic but barytocalcite is monoclinic and paralstonite is trigonal. The species was named Bromlite by Thomas Thomson in 1837 after the Bromley-Hill mine, and alstonite by August Breithaupt of the Freiberg Mining Academy in 1841, after Alston, Cumbria, the base of operations of the mineral dealer from whom the first samples were obtained by Thomson in 1834. Both of these names have been in common use.

Alstonite
General
CategoryCarbonate mineral
Formula
(repeating unit)
BaCa(CO3)2
IMA symbolAsn
Strunz classification5.AB.35
Dana classification14.02.05.01
Crystal systemTriclinic
Unknown space group
Unit cella = 17.38, b = 14.40
c = 6.123 [Å]; α = 90.35°
β = 90.12°, γ = 120.08°; Z = 24
Identification
Formula mass297.42 g/mol
ColourColourless to snow-white; also pale gray, pale cream, pink to pale rose-red
Crystal habitSteep pseudohexagonal dipyramids, pseudo-orthorhombic
TwinningCommon on pseudo-orthorhombic {110} and {310}
CleavageImperfect on pseudo-orthorhombic {110}
FractureUneven
Mohs scale hardness4 to 4.5
LustreVitreous
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity3.70
Optical propertiesBiaxial (−)
Refractive indexnα = 1.526 nβ = 1.671 nγ = 1.672
Birefringenceδ = 0.146
PleochroismNone
2V angleMeasured 6°, calculated 8°
DispersionWeak, r > v
Ultraviolet fluorescenceWeak yellow under LW and SW
SolubilitySoluble in dilute HCl
Alters toColour may fade on exposure to light
Other characteristicsNot radioactive
References
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