Acetyl group

In organic chemistry, acetyl is a functional group with the chemical formula −COCH3 and the structure −C(=O)−CH3. It is sometimes represented by the symbol Ac (not to be confused with the element actinium). In IUPAC nomenclature, acetyl is called ethanoyl.

Acetyl group
Names
IUPAC name
Acetyl (preferred to ethanoyl)
Systematic IUPAC name
Methyloxidocarbon(•) (additive)
Identifiers
3D model (JSmol)
Abbreviations Ac
1697938
ChEBI
ChemSpider
786
PubChem CID
  • InChI=1S/C2H3O/c1-2-3/h1H3 Y
    Key: TUCNEACPLKLKNU-UHFFFAOYSA-N Y
SMILES
  • C[C]=O
Properties
C2H3O
Molar mass 43.045 g·mol−1
Thermochemistry
Std enthalpy of
formation fH298)
−15 to −9 kJ mol−1
Related compounds
Related compounds
Acetone
Carbon monoxide
Acetic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

The acetyl group contains a methyl group (−CH3) single-bonded to a carbonyl (C=O), making it an acyl group. The carbonyl center of an acyl radical has one nonbonded electron with which it forms a chemical bond to the remainder R of the molecule.

The acetyl moiety is a component of many organic compounds, including acetic acid, the neurotransmitter acetylcholine, acetyl-CoA, acetylcysteine, acetaminophen (also known as paracetamol), and acetylsalicylic acid (also known as aspirin).

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